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Acid-catalyzed hydrolysis of some diazoacetophenones in aqueous dioxan

✍ Scribed by C. W. Thomas; L. L. Leveson

Book ID
102444279
Publisher
John Wiley and Sons
Year
1983
Tongue
English
Weight
448 KB
Volume
15
Category
Article
ISSN
0538-8066

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✦ Synopsis

Rate constants and activation parameters for the acid-catalyzed hydrolysis of eight ringsubstituted diazoacetophenones have been measured in three dioxan-water mixtures. An isokinetic relationship applies to the results obtained using a 50% dioxan-water mixture as solvent. Solvent and substituent effects are discussed together with some mechanistic aspects.

Substituent constants are reported for the -COCHN2 group.

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