Medium effect on the reactions of complexes: kinetics and mechanism of the base hydrolysis ofcis-[(salicylato)(amine)bis(ethylenediamine)cobalt(III)] compounds in methanol-water
โ Scribed by Pradyumn K. Mohanty; Ajit K. Parhi; Guru C. Pradhan
- Publisher
- Springer
- Year
- 1996
- Tongue
- English
- Weight
- 419 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0340-4285
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The base hydrolysis of (apS) (salicylato) (tetraethylenepentamine)cobalt(III) has been investigated in MeOH + water and DMSO + water media (0-70% (viv) cosolvents) at 20.0 I t"C I 35.0 and I = 0.10 mol dm-3 (clod-). The phenoxide species [(tetren)Co02CC,H40]' undergoes both OH--independent and OH--c
The kinetics of base hydrolysis of the cis-(chloro)-(benzimidazole)bis(ethylenediamine) cobalt(II1) ion was investigated in Methanol-water and Ethyleneglycol-water media of varying compositions and at isodielectric conditions (Ds = 61 at 25ยฐC) in isopropanol-and Acetonitrilewater media at 35ยฐC in th
The kinetics of the solvolytic aquation of cis-(Bromo) (imidazole) bis(ethy1enediamine) cobalt (111) and cis-(Bromo) (N-methylimidazole) bis(ethy1enediamine) cobalt(II1) have been investigated in aqueous methanol media with methanol content 0-80% by weight and a t temperatures 40-55ยฐC. The pseudo-fi