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Effect of solvent on reactions of coordination complexes. Part 12: Kinetics and mechanism of chloride substitution reactions ofcis-(chloro)(2-aminoethanol)bis(ethylenediamine) cobalt(III) andcis-(chloro)(1-aminopropan-2-ol)-bis(ethylenediamine) cobalt(III) ions in acidic and basic ethylene glycol-water media

✍ Scribed by Anadi C. Dash; Prafulla K. Das; Jyotsnamayee Pradhan

Publisher
Springer
Year
1991
Tongue
English
Weight
431 KB
Volume
16
Category
Article
ISSN
0340-4285

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The kinetics of base hydrolysis of the cis-(chloro)-(benzimidazole)bis(ethylenediamine) cobalt(II1) ion was investigated in Methanol-water and Ethyleneglycol-water media of varying compositions and at isodielectric conditions (Ds = 61 at 25°C) in isopropanol-and Acetonitrilewater media at 35°C in th

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Effect of solvent on the reactions of coordination complexes. Part 10. kinetics of solvolysis of cis(chloro)(1-amino-propan-2-ol)bis-(ethylenediamine)cobalt(III) in methanol + water, propan-2-ol + water, and t-butanol + water media
✍ Anadi C. Dash; Prafulla K. Das 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 574 KB

## Abstract The solvolysis of __cis__(chloro)(1‐amino‐propan‐2‐ol)bis(ethylenediamine)cobalt(III) in aqueous alcoholic media using methanol, propan‐2‐ol, __t__‐butanol as cosolvents, resulted in the formation of the (N,O) chelated product__cis__[Co(en)~2~(NH~2~CH~2~CHOHCH~3~)]^3+^. The pseudo first