Intramolecular electron transfer rates for ion formation in bridged donor/acceptor systems have been determined using fluorescence lifetime measurements. The data show a weak dependence of the rate on the donor/acceptor distance as well as a dependence on the electronic structure of the spacer. Thes
✦ LIBER ✦
Mediator centres and light-induced electron transfer in donor-acceptor systems
✍ Scribed by E.Kh. Brickenstein; M.A. Kozhushner; D.N. Penkov; L.N. Strekova; R.F. Khairutdinov
- Book ID
- 103665753
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 924 KB
- Volume
- 135
- Category
- Article
- ISSN
- 0301-0104
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## Abstract Photoinduced electron‐transfer processes in fullerene‐based donor–acceptor dyads (DBA) in homogeneous and cluster systems are summarized. Stabilization of charge has been achieved through the use of fullerene substituted‐aniline/heteroaromatic dyads with tunable ionization potentials