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Mechanistic Study on the Solution-Phase n-Doping of 1,3-Dimethyl-2-aryl-2,3-dihydro-1 H -benzoimidazole Derivatives

✍ Scribed by Naab, Benjamin D.; Guo, Song; Olthof, Selina; Evans, Eric G. B.; Wei, Peng; Millhauser, Glenn L.; Kahn, Antoine; Barlow, Stephen; Marder, Seth R.; Bao, Zhenan

Book ID: 121333755
Publisher: American Chemical Society
Year: 2013
Tongue: English
Weight: 854 KB
Volume: 135
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja403906d

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## Abstract An efficient method for the synthesis of 2‐aryl‐2,3‐dihydro‐3‐sulfanyl‐1__H__‐isoindol‐1‐ones **1** __via Pummerer__‐type cyclization of __N__‐aryl‐2‐(sulfinylmethyl)benzamides **2** is described. Thus, treatment of these sulfinyl‐benzamides **2**, easily prepared from 2‐(bromomethyl)be