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Mechanistic study on the ionization of trace gases by an electrospray plume

✍ Scribed by Pablo Martinez-Lozano Sinues; Ernesto Criado; Guillermo Vidal


Book ID
113652630
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
463 KB
Volume
313
Category
Article
ISSN
1387-3806

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## Abstract The reaction between salicylic acid and dialkyl phosphite was traced by electrospray ionization mass spectrometry and ^31^P NMR. All reactants, unstable intermediates and products were detected. The mechanism was proposed based on ESI‐MS results and ^31^P NMR profiles.