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Mechanistic Studies on the Hydroxylation of Methane by Methane Monooxygenase

✍ Scribed by Mu-Hyun Baik; Martin Newcomb; Richard A. Friesner; Stephen J. Lippard


Publisher
John Wiley and Sons
Year
2003
Weight
70 KB
Volume
34
Category
Article
ISSN
0931-7597

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Carbon kinetic isotope effect in the oxi
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## Abstract The carbon kinetic isotope effect in the reaction of CH~4~ with OH has an experimentally measured value of 1.003. The measurement was performed using a static system in which the source of OH was the gas‐phase photolysis of H~2~O~2~ with ultraviolet light produced by a high‐pressure mer