Mechanistic studies of the potential oscillation and induction period in the oxidation of formic acid on platinum
β Scribed by Hiroshi Okamoto
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 651 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0013-4686
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π SIMILAR VOLUMES
Simultaneous periodical changes of the potential and the electrochemical quartz crystal frequency response were detected in the course of galvanostatic oxidation of formic acid at a platinized platinum electrode and at a platinized platinum electrode partially covered with poly(aniline) film, respec
The kinetics of oxidation of nitrite to nitrate by peroxornonophosphoric acid in aqueous acid medium have been studied. The observed monotonic fall in rate with increasing pH of the medium has been rationalized on the basis of proton-dissociation equilibria of the substrate as well as the oxidant sp
## Abstract Formic acid molecules highly diluted in argon were passed through a clean platinum screen at 420β730 K and condensed onto an 8βK CsI window. The wellβknown decomposition products, CO~2~, CO, and H~2~O, were observed in the infrared spectra of the resulting matrices. In addition, new abs