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Mechanistic Studies of the Addition of Carbonyl Compounds to Tetramesityldigermene

โœ Scribed by Samuel, Mini S.; Baines, Kim M.


Book ID
127046135
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
34 KB
Volume
125
Category
Article
ISSN
0002-7863

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A theoretical study of malononitrile add
โœ S. El-Taher ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 173 KB ๐Ÿ‘ 2 views

The nucleophilic addition of the malononitrile anion MN to formaldehyde was studied theoretically by the AM1 semiempirical MO method. The addition is found to be endothermic with a late productlike transition state on the reaction coordinate. Additions of MN y to a series of carbonyl compounds were