A theoretical study of malononitrile add
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S. El-Taher
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Article
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1997
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John Wiley and Sons
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English
โ 173 KB
๐ 2 views
The nucleophilic addition of the malononitrile anion MN to formaldehyde was studied theoretically by the AM1 semiempirical MO method. The addition is found to be endothermic with a late productlike transition state on the reaction coordinate. Additions of MN y to a series of carbonyl compounds were