Mechanistic studies of oxygen atom transfer by iron porphyrin complex
β Scribed by W. Nam; K.A. Lee; S.H. Kim
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 69 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0162-0134
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## Abstract Kinetic and spectroscopic analyses were performed to gain information about the mechanism of atomβtransfer radical reactions catalyzed by the complexes [RuCl~2~Cp\*(PPh~3~)] and [RuClCp\*(PPh~3~)~2~] (Cp\*=pentamethylcyclopentadienyl), in the presence and in the absence of the reducing
Ahstiaet-The iron porphyrin ion-complex, which is electrostatic aggregate of iron meso-tetrakis-(N-methyl-4-pyridyl)porphyrin (FeTMPyP, cationic) and iron meso-tetrakis(p-sulfophenyl)porphyrin (FeTPPS, anionic), has a catalytic activity for the reduction of molecular oxygen in aqueous solutions. Rot