Mechanistic Investigation of the Oxygen-Atom-Transfer Reactivity of Dioxo-molybdenum(VI) Complexes
✍ Scribed by Brian W. Kail; Lisa M. Pérez; Snežana D. Zarić; Andrew J. Millar; Charles G. Young; Michael B. Hall; Partha Basu
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 304 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0947-6539
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The asymmetric molybdenum(VI) dioxo complexes of the bis(phenolate) ligands 1,4‐bis(2‐hydroxybenzyl)‐1,4‐diazepane, 1,4‐bis(2‐hydroxy‐4‐methylbenzyl)‐1,4‐diazepane, 1,4‐bis(2‐hydroxy‐3,5‐dimethylbenzyl)‐1,4‐diazepane, 1,4‐bis(2‐hydroxy‐3,5‐di‐__tert__‐butylbenzyl)‐1,4‐diazepane, 1,4‐bis
The mechanism of the oxygen atom transfer reaction mediated by copper-oxygen species has been studied through a substrate-binding ligand approach. Oxidations of copper 5-X-IndPY2 type complexes in which an electron donating (X = OMe) or withdrawing group (X = CN) substitutes the aromatic nucleus in