Mechanistic Studies in Triazolinedione ene Reactions
β Scribed by Georgios C. Vougioukalakis; Michael Orfanopoulos
- Book ID
- 101975990
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 8 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
Ene reaction / Manes, vinyl-/ Triazolinediones / Cycloaddition / Regioselectivity / Diastereoselectivity The ene reaction of 4-methyl-l,2,4-triazoline-3,5-dione stereoselectivity. For the former we invoke preferential clea-(MTAD) with vinylsilanes 1 has been investigated. In all cases vage of the C
The ene reaction of tiazolinedione with unsymmetrical cis-alkenes is regiospecific and shows a preferential abstraction of the allylic hydrogens on the larger alkyl group of the double bond. ## Triazolinedione (PTAD) undergoes the same type of reactions as singlet oxygen (102). It reacts rapidly