The ene reactions of N-phenyl-l.2,4-triazoline-3S-dione (p'f'AD)and singlet oxygen (102) with tetrrrsubstihrted sfkenes,follow regioselectivitytrendsgovernedmairrtyby 1,3-non bondedinteractions(typeI) for the case of ITAD, and mainfyby the steric hindrancecausedduringthe formationof the new doublebo
✦ LIBER ✦
Solvent-Dependent Changes in the Triazolinedione–Alkene Ene Reaction Mechanism
✍ Scribed by Georgios C. Vougioukalakis; Manolis M. Roubelakis; Mariza N. Alberti; Michael Orfanopoulos
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 332 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0947-6539
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The evolution of the u C-C1 bands of the infrared spectrum of a Bernoullian though slightly isotactic poly(viny1 chloride) (PVC), with both the degree of s N 2 substitution reaction with sodium benzenethiolate, as studied earlier, and the increase of the nucleophile infrared bands, has been studied