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Mechanistic pathways of the photolysis of paracetamol in aqueous solution: an example of photo-Fries rearrangement

✍ Scribed by Martignac, Marion ;Oliveros, Esther ;Maurette, Marie-Thérèse ;Claparols, Catherine ;Benoit-Marquié, Florence

Book ID
120511428
Publisher
Royal Society of Chemistry
Year
2013
Tongue
English
Weight
786 KB
Volume
12
Category
Article
ISSN
1474-905X

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An analogue of the photo-fries rearrangement; the photolysis of vinyl benzoate.
✍ R.A. Finnegan; A.W. Hagen 📂 Article 📅 1963 🏛 Elsevier Science 🌐 French ⚖ 191 KB

The classical Fries rearrangement, ' a well known acidcatalyzed process illustrated in equation 1, can be effected in 3-6 the absence of acid catalysts by means of ultraviolet light. OH (1) CsH,OCOR -------) COR + OH Esters successfully rearranged by the photo-Fries reaction include phenyl acetate3