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Mechanistic Insights into the Reduction of Carbon Dioxide with Silanes over N-Heterocyclic Carbene Catalysts

✍ Scribed by Riduan, Siti Nurhanna; Ying, Jackie Y.; Zhang, Yugen


Book ID
120433150
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
468 KB
Volume
5
Category
Article
ISSN
1867-3880

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Conversion of Carbon Dioxide into Methan
✍ Siti Nurhanna Riduan; Yugen Zhang; Jackie Y. Ying 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 307 KB

## Abstract **Activate and reduce**: Carbon dioxide was reduced with silane using a stable N‐heterocyclic carbene organocatalyst to provide methanol under very mild conditions. Dry air can serve as the feedstock, and the organocatalyst is much more efficient than transition‐metal catalysts for this