## Abstract **Activate and reduce**: Carbon dioxide was reduced with silane using a stable N‐heterocyclic carbene organocatalyst to provide methanol under very mild conditions. Dry air can serve as the feedstock, and the organocatalyst is much more efficient than transition‐metal catalysts for this
✦ LIBER ✦
Conversion of Carbon Dioxide into Methanol with Silanes over N-Heterocyclic Carbene Catalysts
✍ Scribed by Siti Nurhanna Riduan; Yugen Zhang; Jackie Y. Ying
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 307 KB
- Volume
- 121
- Category
- Article
- ISSN
- 0044-8249
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## Abstract A broad spectrum of substrates bearing a free allyl moiety can be transformed to carboxylic acids in good to excellent yields and various functionalities are tolerated.