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Mechanistic information from the effect of pressure on the kinetics of some anation reactions of aquopentaamminecobalt(III), -rhodium(III), and -chromium(III) ions in acidic aqueous solution

โœ Scribed by Van Eldik, R.; Palmer, D. A.; Kelm, H.


Book ID
125986024
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
1015 KB
Volume
18
Category
Article
ISSN
0020-1669

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The kinetics of the anation reaction of
โœ P. R. Joubert; R. Van Eldik ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 470 KB ๐Ÿ‘ 1 views

The Co(NH3) 50Hz3+ ion reacts with malonate to form Co(NH3) 50~CCH2C02H2+ or Co(NH3) 50ZCCHzCOz+, depending on the pH of the reaction solution. The kinetics of this anation reaction have been studied as a function of [H+] for the acidity range 1.5 5 pH 5 6.0 in the temperature range of 60 to 8OoC, t