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Mechanistic impact of oxime formation accompanying 1,3-dipolar cycloadditions of nitrile oxides

โœ Scribed by Baran, Janusz; Mayr, Herbert


Book ID
127134889
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
612 KB
Volume
54
Category
Article
ISSN
0022-3263

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The 1,3-Dipolar Cycloadditions of Nitril
โœ Richard Neidlein; Zhihua Sui ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 561 KB

## Abstract The readily available alkyl dicyanoacetates 1 reacted with the 1,3โ€dipolar reagents arenecarbonitrile oxides 2โ€ฒ and arenecarbonitrile imines 5โ€ฒ to afford 1,2,4โ€oxadiazol and 1,2,4โ€triazol derivatives. The arenecarbonitrile oxides 2โ€ฒ with electronโ€donating groups on the arene ring gave p