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Mechanistic consideration of Ti(salen)-catalyzed asymmetric sulfoxidation

✍ Scribed by Bunnai Saito; Tsutomu Katsuki

Book ID
104231837
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
71 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

Asymmetric sulfoxidation using di-m-oxo Ti(salen) complex 2 as the catalyst was revealed to proceed through C 2 -symmetric Ti(salen) complex 6 and peroxo Ti(salen) complex 4 in sequence on the basis of MS and NMR studies of the complexes and the observation of positive non-linear effect.

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