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Mechanistic aspects of the annelation reactions of benzocyclobutenedione monoketals with vinyl organolithium reagents

โœ Scribed by Spangler, Lori A.; Swenton, John S.


Book ID
126962545
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
1005 KB
Volume
49
Category
Article
ISSN
0022-3263

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The mechanistic and synthetic aspects o f the addition reaction of thioxophosphorane sulfenyl bromide with ethyl vinyl ether were studied in detail by N M R techniques. It has been found that the regiospecific, primary product of the reaction, I -bromo-1-ethoxy-2S(dialkoxythiophosphoryl)ethane I , i