Mechanistic and Exploratory Photochemistry. XII. Characterization of the Reactivity of the β-Carbon in the Triplet Excited State of α,β-Unsaturated Ketones 1
✍ Scribed by Zimmerman, Howard E.; Hahn, Roger C.; Morrison, Harry; Wani, M. C.
- Book ID
- 126215809
- Publisher
- American Chemical Society
- Year
- 1965
- Tongue
- English
- Weight
- 379 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0002-7863
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We recently reported the singlet-state photochemical rearrangement of 3-methylene-2,2,5,5-tetramet~lcyclohexanone (1) via a 1,3-sigmatropic acyl shift to 3,3-dimethyl-5-isopropylidenecyclohexanone (g).", However, 17~-acetoyy-4,4-dimetQrl-19-norandrost-5-en-3-one (3)isknown to undergo a triplet-state
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