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Mechanisms of synthesis of maleic and succinic anhydrides by carbonylation of acetylene in solutions of palladium complexes

✍ Scribed by L. G. Bruk; I. V. Oshanina; A. P. Kozlova; O. N. Temkin; K. Yu. Odintsov

Publisher
Springer
Year
1998
Tongue
English
Weight
965 KB
Volume
47
Category
Article
ISSN
1573-9171

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## Abstract The productions of maleic diesters and maleic anhydrides depend on the effect of solvent and acid‐base in palladium‐catalyzed dicarbonylation of terminal acetylenes. For primary and secondary alcohol in benzene, only maleic diesters were obtained stereospecifically from the dicarbonylat