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ChemInform Abstract: Palladium-Catalyzed Dicarbonylation of Terminal Acetylenes: A New Method for Selective Synthesis of Unsaturated Diesters and Maleic Anhydrides.

✍ Scribed by Jinheng Li; Huanfeng Jiang; Mingcai Chen


Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
33
Category
Article
ISSN
0931-7597

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✍ Jin-Hang Li; Huan-Feng Jiang; Ming-Cai Chen πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 356 KB

## Abstract The productions of maleic diesters and maleic anhydrides depend on the effect of solvent and acid‐base in palladium‐catalyzed dicarbonylation of terminal acetylenes. For primary and secondary alcohol in benzene, only maleic diesters were obtained stereospecifically from the dicarbonylat