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Mechanisms of Substitution Reactions at Phosphorus. XII. A Kinetic Study of the Decomposition of Quaternary Phosphonium Hydroxides

โœ Scribed by McEwen, William E.; Axelrad, George; Zanger, Murray; VanderWerf, Calvin A.


Book ID
126293665
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
641 KB
Volume
87
Category
Article
ISSN
0002-7863

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The reaction mechanism of the gas-phase
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## Abstract The kinetics and mechanisms of the gasโ€phase elimination reactions of neopentyl chloride and neopentyl bromide have been studied by means of electronic structure calculations using density functional methods: B3LYP/6โ€31G(d,p), B3LYP/ 6โ€31++G(d,p), MPW1PW91/6โ€31G(d,p), MPW1PW91/6โ€31++G(d