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Mechanisms of peroxide reactions: kinetics of reduction of peroxo-monosulphuric and peroxomonophosphoric acids by iodide ion

✍ Scribed by Secco, Fernando; Venturini, Marcella


Book ID
121333835
Publisher
The Royal Society of Chemistry
Year
1976
Tongue
English
Weight
509 KB
Volume
14
Category
Article
ISSN
1472-7773

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The reaction of peroxomonophosphoric acid and hydrazinium ion in acid perchlorate solutions occurs as per stoichiometry (i), and the rate law (ii) at large [NzH~'], (i) where K& is the first acid dissociation constant of H3P05 and kl and kz are rate constants found to be 2.6 x s-' and 5.0 x lo-' M