Oxygen evolution as a critical test of m
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Cheves Walling; Michael Cleary
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Article
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1977
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John Wiley and Sons
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English
โ 300 KB
๐ 1 views
The stoichiometry of O2 evolution in the Fe3+ catalyzed decomposition of H202 in dilute HCIOa a t high [FeS+]/[H202] ratios is 2H202 -+ 2H20 + O2 with no deficiency indicating accumulation of an intermediate complex. This and the observed kinetics are shown to be consistent with a "redox chain" but