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Mechanisms of formation and decomposition of hypervalent chromium metabolites in the glutathione-chromium(VI) reaction

โœ Scribed by Shadi Moghaddas; Edward Gelerinter; Rathindra N. Bose

Book ID
103569727
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
581 KB
Volume
57
Category
Article
ISSN
0162-0134

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The kinetics of oxidation of N,N-dimethylformamide by chromium(VI) has been studied spectrophotometrically in aqueous perchloric acid media at 20ะŠC. The rate showed a first-order dependence on both [Cr(VI)] and [DMF], and increased markedly with increasing [H ฯฉ ]. The order with respect to [HClO 4 ]