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Mechanisms of Acid Catalysis. The Kinetics and Mechanisms of the Acid-catalyzed Reactions of Ethyl Diazoacetate with Ethanol and Acetic Acid 1

โœ Scribed by Roberts, John D.; Regan, Clare M.; Allen, Inka

Book ID
127287802
Publisher
American Chemical Society
Year
1952
Tongue
English
Weight
612 KB
Volume
74
Category
Article
ISSN
0002-7863

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โœ Xiaodong Xu; Carlos De Almeida; Michael J. Antal Jr. ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 472 KB

In the presence of a low concentration (<O.Ol mol dm-3) of sulfuric acid, ethanol undergoes rapid and selective dehydration to ethene in supercritical water. The kinetics of this reaction are consistent with an acid-catalyzed E2 mechanism.