MECHANISMS OF 1,2-DIOXETANE DECOMPOSITION: THE ROLE OF ELECTRON TRANSFER
β Scribed by K. A. Zaklika; Thomas Kissel; Arthur L. Thayer; Paul A. Burns; A. Paul Schaap
- Book ID
- 114892995
- Publisher
- John Wiley and Sons
- Year
- 1979
- Tongue
- English
- Weight
- 618 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0031-8655
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Thermally stable 1,2-dioxetanes have been synthesized by the reaction of enol-ethers with tris p-bromophenylammoniumyl hexachloroantimonate via a chain oxygenation reaction involving formation of enol-ether cation radicals
The synthesis of the protected phenolate-substituted 1,2-dioxetanes I and 2, containing the substituent directly linked to the peroxidic ring or separated by a methylene group, is reported. The activation parameters and chemiluminescence quantum yield~ upon unimolecular and catalyzed decomposition o