Mechanisms for Manganese(III) Oxidations with Alkenes
β Scribed by William E. Fristad; John R. Peterson; Andreas B. Ernst; Gordon B. Urbi
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- French
- Weight
- 985 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0040-4020
No coin nor oath required. For personal study only.
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## Abstract The oxidation of 4βsubstituted phenyl phenyl sulfides was carried out with several oxo(salen)manganese(V) complexes in MeCN/H~2~O 9β:β1. The kinetic data show that the reaction is firstβorder each in the oxidant and sulfide. Electronβattracting substituents in the sulfides and electronβ