Mild Manganese(III) Acetate Catalyzed Allylic Oxidation: Application to Simple and Complex Alkenes.
✍ Scribed by Tony K. M. Shing; Ying-Yeung Yeung; Pak L. Su
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 35 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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## Abstract Manganese(III) acetate catalyzed oxidative radical‐addition reactions of __α__‐dicarbonyl compounds such as methyl acetoacetate (**6**), acetylacetone (**7**), and dimedone (**8**) to the mixture of 1‐ and 2‐phenylcyclohepta‐1,3,5‐triene (**4** and **5**) were investigated (__Scheme 1__
Two modified Jacobsen-type catalysts were anchored onto an amine functionalised hexagonal mesoporous silica (HMS) using two distinct anchoring procedures: (i) one was anchored directly through the carboxylic acid functionalised diimine bridge fragment of the complex (CAT1) and (ii) the other through