Mechanisms and Kinetics of Reactions of the O(1D, 3P) + CF3Cl System1
โ Scribed by ZHANG, J; SUN, X; CAI, Z; FENG, D
- Book ID
- 123384820
- Publisher
- Elsevier Science
- Year
- 2006
- Tongue
- English
- Weight
- 167 KB
- Volume
- 22
- Category
- Article
- ISSN
- 1005-9040
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๐ SIMILAR VOLUMES
The thermal addition of CF,0sCF3(T 1 to CF2CCl2(E) has been investigated between 49.6 and 69.5"C. The initial pressure of CFJ03CF3 was varied between 7 and 240 torr and that of CF2CC12 between 4 and 600 torr. Four products of formula CF30(E),00CF3, wherej = 1 + 4 are formed. The sum of the products
A laser flash photolysis-resonance fluorescence technique has been employed to study the kinetics of the reaction of O(3P) with CF3NO (kz) as a function of temperature. Our results are described by the Arrhenius expression k z ( T ) = (4.54 ? 0.70) X 10-12exp[(-560 i 46)/T] cm3molecule-'s-' (243 K 5
The rate coefficients for the removal of C1 atoms by reaction with three HCFCs, CF3CHC12 (HCFC-123), CF3CHFCl (HCFC-124), and CH3CFC12 (HCFC 141b), were measured as a function of temperature between 276 and 397 K. CH3CF2C1 (HCFC-142b) was studied only a t 298 K. The Arrhenius expressions obtained ar