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Mechanisms and Kinetics of Nitroxide-Controlled Free Radical Polymerization

โœ Scribed by Fukuda, Takeshi; Terauchi, Tomoya; Goto, Atsushi; Ohno, Kohji; Tsujii, Yoshinobu; Miyamoto, Takeaki; Kobatake, Seiya; Yamada, Bunichiro


Book ID
125457005
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
216 KB
Volume
29
Category
Article
ISSN
0024-9297

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Nitroxide-controlled free radical polyme
โœ Kohji Ohno; Muhammad Ejaz; Takeshi Fukuda; Takeaki Miyamoto; Yusuke Shimizu ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 899 KB

The free radical polymerization of p-tert-butoxystyrene (BOS) in the bulk at 125 "C "initiated" with the adduct of 2-benzoyloxy-l-phenylethyl and TEMPO (BS-TEMPO) was found to proceed in a "living" fashion, providing low-polydispersity PBOS and block copolymers of the type PBOS-b-PS, where TEMPO is