Kinetics of nitroxide-controlled radical polymerization during the non-stationary state
β Scribed by Marco Drache; Kerstin Mandel; Gudrun Schmidt-Naake
- Book ID
- 108249601
- Publisher
- Elsevier Science
- Year
- 2007
- Tongue
- English
- Weight
- 325 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0032-3861
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π SIMILAR VOLUMES
The free radical polymerization of p-tert-butoxystyrene (BOS) in the bulk at 125 "C "initiated" with the adduct of 2-benzoyloxy-l-phenylethyl and TEMPO (BS-TEMPO) was found to proceed in a "living" fashion, providing low-polydispersity PBOS and block copolymers of the type PBOS-b-PS, where TEMPO is
## Abstract **Summary:** Simulations based on the kinetics and mechanism of nitroxideβmediated free radical polymerization (NMP) have been carried out in order to understand the hitherto largely unexplained effects (or lack thereof) of nitroxide partitioning in aqueous miniemulsion NMP. The focus h