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Kinetics of nitroxide-controlled radical polymerization during the non-stationary state

✍ Scribed by Marco Drache; Kerstin Mandel; Gudrun Schmidt-Naake


Book ID
108249601
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
325 KB
Volume
48
Category
Article
ISSN
0032-3861

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πŸ“œ SIMILAR VOLUMES


Nitroxide-controlled free radical polyme
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The free radical polymerization of p-tert-butoxystyrene (BOS) in the bulk at 125 "C "initiated" with the adduct of 2-benzoyloxy-l-phenylethyl and TEMPO (BS-TEMPO) was found to proceed in a "living" fashion, providing low-polydispersity PBOS and block copolymers of the type PBOS-b-PS, where TEMPO is

Nitroxide-Mediated Radical Polymerizatio
✍ Per B. Zetterlund; Masayoshi Okubo πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 140 KB

## Abstract **Summary:** Simulations based on the kinetics and mechanism of nitroxide‐mediated free radical polymerization (NMP) have been carried out in order to understand the hitherto largely unexplained effects (or lack thereof) of nitroxide partitioning in aqueous miniemulsion NMP. The focus h