Mechanism of β-Silyl Diacyl Peroxide Decomposition: A Mild and Stereoselective Synthesis of β-Silyl Esters
✍ Scribed by Masterson, Douglas S.; Porter, Ned A.
- Book ID
- 126999444
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 156 KB
- Volume
- 69
- Category
- Article
- ISSN
- 0022-3263
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## Abstract For Abstract see ChemInform Abstract in Full Text.
The addition of trimethylsilyloxy phosphorus (Ill) derivatives, generated in situ, to ct-haloacrylates and acryiordtriles at room temperature provides a mild, general and stereoselective route to 13-phosphonoacrylates.