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Mechanism of the thermolysis of benzoyloxymethyl phenyl sulfoxide. New sulfoxide fragmentation reaction

โœ Scribed by Maricich, Tom J.; Jourdenais, Richard A.; Harrington, Clinton K.

Book ID
127188414
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
254 KB
Volume
95
Category
Article
ISSN
0002-7863

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We have recently reported that treatment of the C3(-hydroxyaldehyde dlphenylmercaptals (I) with methyl-or n-butyllithlum leads to the formation of the corresponding phenylthlomethyl ketone In high yield.' This reaction Is considered to proceed through an Initial formation of the dlllthlated lntermed