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Sulfoxide-carbodiimide reactions. X. Mechanism of the oxidation reaction

โœ Scribed by Moffatt, John G.


Book ID
127358593
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
532 KB
Volume
36
Category
Article
ISSN
0022-3263

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Mechanism of sulfoxide-ketenimine and su
โœ Robert E. Harmon; Carmen V. Zenarosa; S.K. Gupta ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 218 KB

In a recent c ommunication we have described the usefulness of sulfoxide-ketenimine in the oxidation of 2:Jb\_-isopropylideneadenosine.1 We have now extended this new procedure to the oxidation of hydroxy.steroids. This is exemplified by the oxidation of testosterone to androst-4-ene-3,17-dione. Wit