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Mechanism of the thermal decomposition of substituted tetraoxanes in benzene solution: effect of substituents on the activation parameters of the unimolecular reactions

✍ Scribed by Cafferata, Lazaro F. R.; Eyler, G. N.; Svartman, E. L.; Canizo, A. I.; Borkowski, E. J.


Book ID
120527518
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
465 KB
Volume
55
Category
Article
ISSN
0022-3263

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Effect of substituents on the kinetic en
✍ Helena FlorΓͺncio; Peter C. Vijfhuizen; Wigger Heerma; Geo Dijkstra πŸ“‚ Article πŸ“… 1979 πŸ› John Wiley and Sons 🌐 English βš– 288 KB

## Abstract The kinetic energy relased on the loss of a CH~3~ β‹… radical from __para__ substituted anisoles appears to depend on the nature of the substituent. The application of the dual parameter equation of Yukawa and Tsuno yields a linear correlation with the __T__~0.5~‐values. The mesomeric eff