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Mechanism of the sulfuric acid-catalyzed rearrangement of methyl and carbonyl carbon-14-labeled 3,3-dimethyl-2-butanone

โœ Scribed by Bhatia, Kishan; Fry, Arthur


Book ID
126418470
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
805 KB
Volume
34
Category
Article
ISSN
0022-3263

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## Abstract The mechanism of reaction between 3โ€hydroxyโ€3โ€methylโ€2โ€butanone and malononitrile for the synthesis of 2โ€dicyanomethyleneโ€4,5,5โ€trimethylโ€2,5โ€dihydrofuranโ€3โ€carbonitrile catalyzed by magnesium ethoxide was investigated by density functional theory (DFT). The geometries and the frequenci