𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Mechanism of the Reppe cyclooctatetraene synthesis from ethyne: a labeling experiment

✍ Scribed by Colborn, Robert E.; Vollhardt, K. Peter C.

Book ID
120492193
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
426 KB
Volume
103
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Cyclooctatetraene dianion from 1,5-cyclo
Cyclooctatetraene dianion from 1,5-cyclooctadiene. A synthesis in the presence of naphthalene radical anion
✍ Leslie H. Simons; J.J. Lagowski πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 French βš– 58 KB

A novel synthesis of cyclooctatetraene dianion from 1,5-cyclooctadiene (1,5-COD) is described. The reaction of the potassium-naphthalene adduct with 1,5-COD proceeds at room temperature over 3 days in heptane/tetrahydrofuran to produce the target compound.