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MECHANISM OF THE REACTION OF NITROMETHANE WITH BASES

✍ Scribed by Drew, Charles M.; McNesby, James R.; Gordon, Alvin S.


Book ID
127331651
Publisher
American Chemical Society
Year
1954
Tongue
English
Weight
131 KB
Volume
76
Category
Article
ISSN
0002-7863

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The reactions of hypochlorites with olef
✍ V.L. Heasley; G.E. Heasley; M.R. McConnell; K.A. Martin; D.M. Ingle; P.D. Davis πŸ“‚ Article πŸ“… 1971 πŸ› Elsevier Science 🌐 French βš– 264 KB

In a recent attempt to add t-butyl hypochlorite to olefins such as styrene and l-hexene in nitromethane, we were surprised to find that the exclusive products of these rapid reactions are chloronitromethane (ClCHaNO =,I) and t-butyl alcohol in nearly quantitative yield. This reaction is outlined in