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Mechanism of the oxygen disproportionation of ditert-alkylniteoxyl radicals

โœ Scribed by V. A. Golubev; V. D. Sen'; I. V. Kulyk; A. L. Aleksandrov


Book ID
112440296
Publisher
Springer
Year
1975
Tongue
English
Weight
577 KB
Volume
24
Category
Article
ISSN
1573-9171

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Several attempts have been made to correlate the disproportionation and the combination rate constant ratio, k,/k,, of the alkyl radicals with the entropy change of the processes [ 1-31. Bradley [I] made a specific suggestion that the k,/k, ratio is a function of the entropy change of the processes