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Mechanism of the oxidation of glyoxylic and pyruvic acids by periodate

✍ Scribed by Maros, L�szl�; Moln�r-Perl, Ibolya; K�v�r, L�szl�

Book ID
126589575
Publisher
Royal Society of Chemistry
Year
1976
Tongue
English
Weight
656 KB
Volume
12
Category
Article
ISSN
1472-779X

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Mechanistic studies on the oxidation of
Mechanistic studies on the oxidation of glyoxylic and pyruvic acids by a {Mn3O4}4+ core in aqueous media
✍ Pulak Chandra Mandal; Suranjana Das; Subrata Mukhopadhyay 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 194 KB 👁 1 views

## Abstract In aqueous media, the Mn^IV^ trimer [Mn^IV^~3~(μ‐O)~4~(phen)~4~(H~2~O)~2~]^4+^ (1, phen = 1,10‐phenanthroline) equilibrates with its deprotonated from [Mn~3~(μ‐O)~4~(phen)~4~(H~2~O)(OH)]^3+^ (2). Among the several synthetic multinuclear oxo‐ and/or carboxylato‐bridged manganese complexe