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Mechanism of the olefin metathesis reaction. 4. Catalyst precursors in tungsten(VI) based systems

✍ Scribed by Mocella, M. T.; Rovner, R.; Muetterties, E. L.

Book ID
121018535
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
307 KB
Volume
98
Category
Article
ISSN
0002-7863

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The c a t a l y t i c and spectroscopic properties o f the photochemically a c t i v a t e d metathesis c a t a l y s t system W(C0),/TiX4/hw ( X = C l . Br. I) have been studied. A l l evidence i n d i c a t e s a high resemblance w i t h the chemically a c t i v a t r d Y(CO)6~xLx/RAlC12/02 system