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Mechanism of the N -Cyclopropylimine-1-pyrroline Photorearrangement

✍ Scribed by Sampedro, Diego; Soldevilla, Alberto; Rodríguez, Miguel A.; Campos, Pedro J.; Olivucci, Massimo

Book ID
127257000
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
312 KB
Volume
127
Category
Article
ISSN
0002-7863

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📜 SIMILAR VOLUMES

Simple and versatile synthesis of 1-pyrr
Simple and versatile synthesis of 1-pyrroline derivatives through thermal rearrangement of N-cyclopropylimines
✍ Pedro J. Campos; Alberto Soldevilla; Diego Sampedro; Miguel A. Rodrı́guez 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 121 KB

N-Cyclopropylimines rearrange under thermal conditions to give 1-pyrrolines. The effect of imine and cyclopropane substitution is explored. This methodology allows the presence of different substituents (alkyl, alkenyl, aryl) and the reaction proceeds regiospecifically.