Mechanism of the inhibition of polymerization of vinyl monomers initiated by benzoyl peroxide by stable nitroxide radicals
β Scribed by A.V. Trubnikov; M.D. Gol'dfein; N.V. Kozhevnikov; A.D. Stepukhovich
- Book ID
- 118967755
- Publisher
- Elsevier Science
- Year
- 1983
- Weight
- 467 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0032-3950
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Almtract--It is found that the interaction of geminal bis-sulphides with acyl(aroyl)peroxides forms systems which initiate polymerization in non-aqueous media. The mechanism of the reaction of benzoyl peroxide with bis(amylthio)methane was studied. The initiation is shown to result form the products
The polymerization of methyl methacrylate in benzene was initiated by benzoyl peroxide and examined by kinetic analysis particularly from the point of view of primary radical termination. It is concluded that the velocity constant for dissociation of the benzoyloxy radical to give the phenyl radical