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Initiating radical polymerization of vinyl monomers by silicon peroxides

✍ Scribed by Yu.D. Semchikov; N.A. Kopylova; N.V. Yablokova; L.N. Nistratova


Book ID
107754059
Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
294 KB
Volume
22
Category
Article
ISSN
0014-3057

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Polymerization of vinyl monomers initiat
✍ Yu.I. Puzin; G.V. Leplyanin; Yu.M. Shaul'skii; G.A. Tolstikov πŸ“‚ Article πŸ“… 1988 πŸ› Elsevier Science 🌐 English βš– 300 KB

Almtract--It is found that the interaction of geminal bis-sulphides with acyl(aroyl)peroxides forms systems which initiate polymerization in non-aqueous media. The mechanism of the reaction of benzoyl peroxide with bis(amylthio)methane was studied. The initiation is shown to result form the products