Mechanism of the electroreduction of glycol aldehyde on the DME
β Scribed by E. Kirowa-Eisner; E. Gileadi
- Publisher
- Elsevier Science
- Year
- 1972
- Weight
- 600 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0022-0728
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β¦ Synopsis
The actual slope obtained in the same system for the reduction of Cd 2+ which is known to be purely diffusion controlled, was 0.19.
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The electroreduction behaviour of 1,2-, 1,4-, 1.3-dicyano-and 1,3,5-tricyanobenzenes in acetonitrile was investigated. The mechanism for the electroreduction of these compounds was proposed using the results of cyclic voltammetry, rotating disc voltammetry, dc and differential pulse polarography and
## Abstract A new mechanism is proposed for gasβphase O~3~βaldehyde reactions. Certain aspects of the new mechanism may be applicable also to O~3~βaldehyde reactions in solution. The proposed mechanism involves initiation by addition of O~3~ across the aldehydic Cο£ΎO bond. The initiation process and