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Mechanism of the Electrodeposition of Cobalt(II) Thiocyanate in N,N-Dimethylformamide (DMF) Solution and Effect of Chloride Ions

✍ Scribed by Cui, C. Q.


Book ID
121387806
Publisher
The Electrochemical Society
Year
1991
Tongue
English
Weight
736 KB
Volume
138
Category
Article
ISSN
0013-4651

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The rate of the solvent substitution reaction, CoCl 3 S Γ€ +Cl Γ€ YCoCl 4 2Γ€ +S (S-solvent) has been studied by means of stopped flow spectrophotometry in dimethyl sulfoxide (DMSO) and N,N-dimethylformamide (DMF), and the rate constant k f , and the activation enthalpy D f H p and entropy D f S p have